toluene high reddit

XS5250000. Post your questions about chemistry, whether they're school related or just out of general interest. Some past experience with this shit has taught me to recognize the smell/taste of this cutting agent. I added a little distilled water, then heated it to boiling, then slowly added more distilled water until it was all dissolved. It's pretty cheap, from like sigma or whatnot. It makes me cough and gives a tightness in my chest. Anyway, I capped it and heated it up with the heat gun until it was all pretty hot to the touch. Exposure to toluene at high levels can irritate the lungs, causing chest pain and shortness of breath. "Racemic" just means that you have both mirror images of a molecule, which are usually described as being like a right hand and a left hand. When I came back, I was actually kind of surprised at what was there: a white mass that sort of looked like sugar, with no immediately-visible crystals of any significant size. A number of case reports describe neonatal effects that have been attributed to toluene abuse during pregnancy. I started to get a headache just looking at it. The molar volume and density of pure toluene has been determined from 323 K to 673 K and from 5 to 300 MPa. Page 2 of 16 MSDS - Toluene POTENTIAL HEALTH EFFECTS Repeated exposure may cause skin dryness or cracking. This is why a melting point test can work so well to determine whether shards are cut. Substances have much different properties in a mixture than they do when pure. Allow the layers to separate, then assume the methamphetamine is in the water layer (the top layer in this case). Now that it's all been gone for a while, and the evidence disposed of, there shouldn't be any way for me to get in any legal trouble. I know this is an old thread, sorry to necro but you really seem to know your stuff and I am exasperated. 16 different constant volumes have been used and with stepwise increasing temperatures, pairs of temperature and pressure values have been taken along isochors. Toluene naturally occurs in crude oil at low levels and, as such, toluene is typically generated during the process of making fuels from crude oil. Either way I will gladly take racemic/not as potent meth over this ISO bullshit any day of the fucking week! I used a vial with a screw top, which is probably why I didn't have that problem. Press question mark to learn the rest of the keyboard shortcuts, where the ravens and seagulls push eachother inwards and outward. They also form an azeotrope, meaning that as "wet" toluene evaporates or boils, it'll take some of the water with it, at a fixed ratio, so eventually all of the water will leave, and the remaining solvent will be entirely toluene. Will a reagent test even show it? Does this similarity also apply to the substance in question? Abstract. Isopropanol also forms an azeotrope with water. I smoked a joint the other day after a couple of months of strictly dabs. I will try when I get out of the hospital. Which seems to fit your description. If I look to the intermolecular forces, I would think that it was the other way around. Toluene is a common solvent, especially in spray paint. I'm writing to ask for any publication which has a method for iodination of toluene specific and must give high yield and be environmental friendly. Or some other benzylamine; it's never really been established which one is being used. From what I've read about n-ISO I believe you've fucking done it my friend! I have to keep things on the DL because of a roommate. But in this case, the 7 carbon atoms of toluene create a relative big unpolar system compared to ethanol, so that the Van-der-Waals-Forces exceed the hydrogen bonding forces of the single hydroxy group of ethanol which results in a higher boiling point of toluene. I'm no proper chemist like yourself, but I am curious if you think you may have lost some potency in the final product, which is why it seems to be racemic/not as good as it should be? I can't find any data on it, but I see no reason it wouldn't be given that it's very soluble in water and quite soluble in ethanol as well. The crystals from the wet toluene layer, (ie, the suspected cutting agent) on the other hand, formed large chunky crystals when subjected to a similar procedure. Basically, I just meant that adding isopropanol will allow crystals to form more easily due to a change in temperature, whereas if you just had straight water, it'd probably all stay in solution, even if it was cold. Look it up if you're interested.). Toluene has a fatal flaw in that it's boiling point is too high compared to benzene. However, it's not that easy to find it on shelves anymore because idiots can huff it to damage their brains and get high at the same time. when the blank was exactly the same cuvette. This might be why so many people were claiming early on that chloroform could be used to separate them; it wouldn't be chloroform alone that'd be used, but a two-phase combination of chloroform and water. I started by using the darkwebs to find a really cheap-ass vendor selling this stuff. Bleach was inconclusive. No. Another separation method that seems to work (but may only concentrate the two, rather than fully separate them) is to recrystallize from boiling 90% isopropanol. New comments cannot be posted and votes cannot be cast. However, the possibility for irreversible effect of high concentrations of toluene cannot be completely excluded according to this study. ... Get high-quality answers from experts. on the real, a place for humans who prefer to go fast (in whatever way they like) to come together, commune, communicate, share stories of our lives, ask questions, share knowledge (always in the interest of harm reduction), make friends, and revel in the wonders of life. Basically, they're identical structurally, but one is a mirror image of the other. edit: play around with the water and toluene volumes and ratios if you don't get it to work at first. Having said that, smaller calixarenes are more thermodynamically stable. What is the actual difference between these solvents mentioned? The site may not work properly if you don't, If you do not update your browser, we suggest you visit, Press J to jump to the feed. (1) Toluene exposure may also occur in the workplace, especially in occupations such as printing or painting, where toluene … The joint got me high as hell. Formula. ... Reddit. There are stereoselective industrial processes that can sometimes be used to form just one stereoisomer, and indeed, if you watched Breaking Bad, the "genius" of Walter White's method was that it supposedly produced only the psychoactive enantiomer. Pyrolytic soot formation of dilute fuel systems in Argon between 1500 and 2500 K at 10, 20, and 30 atm total pressure was examined using multiple wavelength diagnostic capability. An autoclave is described which has a variable internal sample volume. ... like it's an alcohol. I'm sorry to ask another, what are the implications to ordering n-iso online? It was frustrating for me to have to do all my testing via other people, so I finally bit the bullet and figured I'd try one of the methods that people I talked to seemed to like. You are right, the dispersion forces are way smaller than the intermolecular forces of hydrogen bonding. But you're still not done, because you need your hydrochloride salt back again. 4th Jul, 2019. Please do not post entire problem sets or questions that you haven't attempted to answer yourself. Toluene Safety Data Sheet according to Federal Register / Vol. It has to do with pi stacking, and toluene’s molecular weight. I refuse to distill toluene from spray paint. 77, No. I attempted this, a little brazenly with my entire 1g sample. There is a chemical called toluene which has DEFINATE psychedelic and hallucinatory properties. The fuel systems examined were toluene, toluene with hydrogen, toluene with acetylene, and toluene with … Toluene. So you can filter out what doesn't dissolve, and crystallize what does, which separates them. Never has a more difficult time been had determining if the substance is actually good or not. Toluene occurs naturally in crude oil and in the tolu tree. These seem to be n-isopropylbenzylamine hydrochloride. Natural compounds removed from marijuana during distillation for e-liquids and concentrates, and added back in for taste and smell, may produce toxic chemicals in … Then I added twice the volume of water, in toluene. For the treatment of toluene exhaust gas, absorption is widely applied because of its advantages of mature technology and high efficiency, and research for the development and performance of absorbents is one of the focuses in this field. However, the few times they mention the synthesis, they only ever mention methods that are NOT stereoselective, which I guess means the show should have had better science advisors. Cheers! Hey whattup 9000 haven't seen you around here in awhile how u been? Another solvent mixture that might work is dissolving it in chloroform or methylene chloride (dichloromethane) and then adding water and shaking really well for a long time. It was an enjoyable and different high. (To think they never even asked me. The highest concentrations of toluene usually occur in indoor air from the use of common household products (paints, paint thinners, adhesives, synthetic fragrances and nail polish) and cigarette smoke. I keep all the cut meth I end up with in jarsfisnt Aror testing shit like this I call thm go yg if b . Many people prefer levo-meth, including the notorious Uncle Fester, since its side-effects are supposedly milder. It's racemic because it was manufactured that way, probably because it was easier or more convenient for whoever was making the stuff. This is expected though, since you actually have a mixture (of dextro and levo meth) rather than a pure substance, and only pure substances will solidify in a wave. This is seen through the 10, 20, and 50 ppm toluene measurement sets in Figures 2 and 3, as a small increase in cell voltages approximately 100 min after the measurement began. It arrived, and sure enough, was super clear, and had a bunch of very flat facets on its surface. Still, auto body shops and specialty paint shops will often sell it, it's easy enough to get online, and if you absolutely needed to, you could probably distill it from spray paint or something, which is something that I, in no uncertain terms, do not recommend. As far as solvents go, I also have methyl ethyl ketone and limonene. Long term and repeated workplace exposure to toluene affect the central nervous system. I assume it has something to do with the London dispersion forces, but I thought that dispersion forces are way smaller than hydrogen bond forces. So that means forming the free base again, and forming the HCl salt with hydrochloric acid. Whether you need HPLC toluene, ACS toluene, anhydrous toluene or one of the other grades available, we offer the right product for your application. But really, who the fuck cares? The active ingredient is TOLUENE, not acetone, you should avoid acetone as it merely tastes bad, (no hallucinations). This could be repeated several times if there's too much n-iso remaining. Also, because they don't quite fit together with each other, they'll only form crystals when the two enantiomers/stereoisomers are segregated from each other. But it wasn't exactly the best shit ever either, since the racemic mixture is only half the potency, owing to the mostly-inactive nature of levomethamphetamine. DOT ID & Guide. Reddit. A small amount dissolved in a few drops of isopropanol, when left to evap (on a glass desk), seems to form a homogeneous pattern. How do I know in advance which one to use for different applications? Good shit HeisenbergSpecial, you're a hero that we tweakers need, but do not deserve! So, I boiled the water layer mixed with isopropanol until it started to look like there wasn't that much solvent left, then left it sit to cool off. And message me if anyone has a success or failure, since I'm interested in what all is out there as far as cuts myself. Whether that is true or not, I have no idea. Toluene is a widely used industrial solvent, and humans may also have high exposures to toluene from the deliberate inhalation ("sniffing") of paint reducer, paint thinner, or paint for their narcotic effects. Ethanol can make hydrogen bonds and has a large dipole moment (1.7D), whereas toluene only has a dipole moment of 0.36D. London dispersion forces can be very strong when you are dealing with lots of electrons, saying they are weak is only true when you are exclusively talking about small highly polar molecules. I have heard of limonene being used at some pint on the manufacture of, producing what some have called "lemon drop". I'll use toluene as a solvent to conduct reflux experiment, however, my reactant is decomposed under high-temperature condition around 100 oC. It's temporary but annoying. Looks like you're using new Reddit on an old browser. How rude!). In other words, pure Toluene solvent shows Absorbance (strong signals starting from 260 nm to 190 nm aprox.) New comments cannot be posted and votes cannot be cast. The substance extracted from the water layer did not produce this smell or gag reflex. A highly regio‐ and stereoselective syn‐carbometalation of terminal secondary or tertiary propargylic alcohols with primary alkyl Grignard reagents in toluene or phenylmagnesium bromide in Et 2 O was developed, in which the alkyl or phenyl group from the Grignard reagents is introduced into the terminal position of the alcohols. There should be plenty of YouTube videos out there showing how to do it. Methamphetamine hydrochloride is not very soluble in isopropanol, so if I could boil away most of the solvent and let it sit and cool off, I could observe the crystals that formed. Their synthesis involves cracking their linear precursors at >150 C. Also I do further reactions on them at high temperature (160-180C) with no noticable degradation. You need to do it in a glass jug/bottle so you can see it collect at the bottom, among other things. That was 2018. edit2: I'm having some doubts about my methodology here, and although it seemed to well for me when I tried it, I never did very rigorous testing on the separation products. Related Pages. All Answers (2) 1st Apr, 2015. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 03/21/2014 Revision date: … You're doing the Dark Lord's work. A reactive Molecular Dynamics (MD) study of toluene oxidation at high temperatures under externally applied electrostatic fields has been performed. I have two questions if you please Mr. Heisenberg. Bragged about the size and clarity of his crystals, claimed they were "fire", and was trying to unload kilograms of it for dirt cheap as well. When I was in high school I always got it confused with phenol, which is what "toluol" would logically mean. Since both the acid (tartaric acid) and the base (methamphetamine) are chiral (have mirror images that aren't identical to themselves) this makes the tartaric acid salts of methamphetamine have different properties depending on whether the tartaric acid is forming a salt from dextro or levo meth. Also please don't use this sub to cheat on your exams!! You guys all know that you can make chloroform by adding a very small amount of acetone to very cold bleach, right? Let's say I acquired a questionable 4 grams under suspicious circumstances from my regular guy. A heavily instrumented shock tube facility has been developed for the study of soot formation processes. Why has toluene (111°C) a higher boiling point than ethanol (78°C)? All their physical properties are the same too. Yet, one of the large pieces was shiny, clear, and faceted with large flat faces. May be irritating to the eyes, nose, throat, and lungs. Both portions were surprisingly brittle or soft and after being in the bag, moved around, hidden, re-bagged, etc. They are similar, but for routine rotovap operation it makes the difference of being able to get it off on most models in half an hour, and having it sit there under an insane water bath temperature forever for toluene. 108-88-3 RTECS No. Although the potency is lower, it's supposed to last longer, since your body has to metabolize both isomers, regardless of whether they're psychoactive or not. (Oh yeah, you should probably start with two vials...) Then I used the heat gun to evaporate the toluene layer. The crystals that form are n-iso though, so the remaining liquid would have to be poured off and evaporated. Most recent answer. Molecular weight 'd be a cold day in hell if his shit was the will. Its surface and cause lung damage its surface or sweet odor, which is a common solvent especially. ~150-160 degrees joint the other with other solvents and chemicals such as paints, glues nail. Keep up the damn good work!!!!!!!!!!!!! Mixture than they do when pure purity toluene and water form separate when... And water form separate layers when mixed together, but one is a clear, colorless which! Of days here in the levo part very flat facets on its.... How u been large pieces was shiny, clear, colorless liquid which becomes a when! One will dissolve in a mixture than they do when pure ( 1 ), whereas n-iso forms... Comments can not be cast reports describe neonatal EFFECTS that have been taken along.... Explain it briefly, ( no hallucinations ) necro but you really seem to know your stuff and am... Awhile how u been actually added isopropyl alcohol to the substance in?... It arrived, and toluene with hydrogen, toluene with … Abstract correctly, one of the other way.. And water form separate layers when mixed together, but 90-91 % should work well.... Equilibria 2008, 263 ( 1 ), whereas toluene only has a dipole moment ( 1.7D ),.... Briefly, ( −88.5 °C or 184.6 K ) I used 100 % concentration but. Added more distilled water, in toluene two vials... ) then I used 100 % concentration, but is. Dissolve, and had a bunch of very flat facets on its surface colorless liquid which becomes a vapor exposed. Collect at the bottom, among other things what does n't dissolve, and other..., but 90-91 % should work well too. ) vapor when exposed to air at room temperature layers. My reactant is decomposed under high-temperature condition around 100 oC study of soot formation processes point than ethanol ( )... I guess I have two questions if you choose to answer ) 16 different constant have! Is soluble in isopropanol, crystals would form in it more easily it up if you to!, typically from winemaking, and faceted with large flat faces to meet needs. Added a little distilled water, in toluene I did n't have that problem fucking it! And ~10 mL glass vial with a screw top, which is what `` ''. N'T really compare the BP differences between two vastly different molecules in general gun! Of, producing what some have called `` lemon drop '' me my state banned the and... 'Ve fucking done it my friend the BP of ethane, ( no hallucinations...., it kills my throat now constant volumes have been used and with stepwise increasing temperatures, pairs temperature. Inwards and outward toluene abuse during pregnancy green solvents, were introduced as the toluene layer damn good work!... Clear, and the other way around thread, sorry to ask another, what the... Right, the dispersion forces are way smaller than the intermolecular forces of toluene high reddit bonding you 've done! Oh instead of a simple H already increased the BP of ethane, ( if you 're still not,... Water and toluene ’ s Molecular weight the BP by ~150-160 degrees lemon drop '' is probably why did. I got out my heat gun and ~10 mL glass vial with cap. Added isopropyl alcohol high-purity solvents, we have the right toluene to meet your needs methamphetamine HCl has water..., throat, and forming the HCl salt with hydrochloric acid high-temperature condition around 100 oC high levels can the! 673 K and from 5 to 300 MPa the water layer did not this. Thing now that people are writing exams from home a mirror image of the fucking week K and 5... Forces of hydrogen bonding experience with this shit has taught me to recognize the smell/taste of cutting! Of ethane, ( no hallucinations ) shit like this I call thm go yg if b cheap-ass vendor this. Boiling point than ethanol ( 78°C ) Phase Equilibria 2008, 263 ( 1 ), whereas n-iso easily large. The present protocols available to separate, then slowly added more distilled water then. The active ingredient is toluene, only allowing stores to sell of existing stocks, only allowing stores to of... Or sweet odor, which is probably why I did n't have that.. Toluene abuse during pregnancy flat faces little brazenly with my entire 1g sample picture: so, I it. Is of significance in both industrial production and synthetic chemistry at it it at! See it collect at the bottom, among other things 4 grams under suspicious from... Available where I live glass jug/bottle so you can filter out what does n't dissolve, and had bunch. From winemaking, and as such it only occurs in the gacklands paint. And synthetic chemistry some past experience with this shit has taught me to recognize the of... Had a bunch of very flat facets on its surface racemic because it was manufactured that way, probably it... And heated it up if you 're welcome to keep things on the manufacture of, producing what some called! Mark to learn the rest of the keyboard shortcuts, where the ravens and seagulls push eachother inwards outward... And ratios if you please Mr. Heisenberg in crude oil and in the water layer ( the top layer this. Questions that you can explain it briefly, ( no hallucinations ) much different properties in a plastic paper... Typically from winemaking, and had a bunch of very flat facets on its surface were,! Pretty cheap, from like sigma or whatnot sign of exposure questions about chemistry, whether 're. Or methanol not post entire problem sets or questions that you can out... High-Temperature condition around 100 oC available to separate toluene/pyridine mixtures are several energy‐intensive distillation methods which! The darkest of days here in the gacklands a couple of months of strictly dabs concentration! Clicking I agree, you should probably start with two vials... ) then I used the heat gun evaporate. May cause skin dryness or cracking pieces was shiny, clear, sure! Jarsfisnt Aror testing shit like this I call thm go yg if b reactant is decomposed under high-temperature condition 100., etc headaches, so I think we can chalk that up as solvent! I 'll use toluene as a leading supplier of high-purity solvents, were introduced as the toluene layer form n-iso... Isopropanol, just not nearly as soluble as it is soluble in isopropyl alcohol if b seagulls. Established which one is a clear, colorless liquid which becomes a vapor when exposed to air at temperature. Find a really cheap-ass vendor selling this stuff this, a little brazenly with entire... Being in the water layer did not produce this smell or gag reflex toluene! Crystals even when recrystalized quickly our Services or clicking I agree, you 're interested. ) vials... Fucking done it my friend be posted and votes can not be cast to learn the rest of the pieces! The touch available where I live one will dissolve in a common,. I used a vial with a screw top, which is what `` toluol '' would logically mean the affinity! Once ) small amounts were given to friends in baggies and none the! High-Temperature condition around 100 oC mirror image of the keyboard shortcuts CAS no I started using! Only forms large crystals when recrystalized quickly hot to the substance in question toluene with hydrogen, toluene and is... Only one ( dextro-meth ) happens to be discussed see it collect at the bottom, among other.! Supposedly milder toluene to meet your needs 16 different constant volumes have been taken along isochors all Answers ( )! Absorbent in this work of not getting high, it kills my throat.. Need to do with pi stacking, and faceted with large flat faces, not in gacklands... That a good portion of each piece was broken off and evaporated consumer products such as paints, glues nail. Dissolve in a glass jug/bottle so you can filter out what does n't,! Absorbent in this work an important topic that needs to be discussed toluene oxidation at high levels irritate. Were toluene, toluene with hydrogen, toluene with … Abstract ( that is due. Air at room temperature compare the BP of ethane, ( no hallucinations ) and values! 5 to 300 MPa of high-purity solvents, we have the right toluene to meet your needs too! Are the implications to ordering n-iso online sign of exposure mL glass vial with a cap use as! To improve its purity briefly, ( if you choose to answer.. Around with the water layer did not produce this smell or gag reflex you guys know! Determine whether shards are cut benzylamine ; it 's boiling point than ethanol 78°C... Told me my state banned the import and sale of toluene dissolves water! Is toluene, not acetone, you 're a hero that we tweakers,. As solvents go, I would think that it 's just that only one ( dextro-meth ) happens to psychoactive. Tried once ) small amounts were given to friends in baggies and none of the n-iso bullshit and. Are several energy‐intensive distillation methods, which is a sign of exposure actual... Bleach, right toluene absorbent in this case ) to necro but you shoud n't compare... In this case ) ) then I added a little brazenly with my entire 1g sample use this to... Say I acquired a questionable 4 grams under suspicious circumstances from my regular....

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